Transformation of the hydride-containing dinitrosyl iron complex [(NO)2Fe(η2-BH4)]- into [(NO)2Fe(η3-HCS2)]-

Other Title
Via reaction with CS2
Journal
Dalton Transactions
Date Issued
2019-01-01
Author(s)
CHIEN-HONG CHEN
DOI
URI
Abstract
Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4]- affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)]- (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)]-, the first DNIC featuring both linear/bent NO ligands and Fe 3d z2-to-HCS2 π∗ backbonding interaction.
Type
journal article