CHI-YUAN LU2026-10-162026-10-162007-05-01Pure ID: 15337682Pure UUID: 8922d295-3f3f-44e4-851d-092005ca7e2010.1016/j.fuel.2006.09.022https://www.scopus.com/pages/publications/33846215178https://scholars.csmu.edu.tw/handle/123456789/32653A carbon nanotube (CNT) was used as catalyst support impregnated with transition metal cobalt for CO oxidation at low temperature. Catalyst properties were analyzed by X-ray powder diffractometer (XRD), X-ray photoelectron spectrometer (XPS), and transmission electron microscope (TEM). Analytical results for TEM and XRD demonstrated that cobalt particles were highly dispersed on the carbon nanotube (20-30 nm) with nanosized cobalt particles (10-15 nm). These investigations indicated that Co/CNT generates about 99% of the high activity for CO conversion at 250 °C and thermally stability that is superior to Co/activated carbon (AC). The optimum reaction conditions for CO conversion were O2 concentration 3%, operation temperature 250 °C, CO concentration 5000 ppm, and space velocity 156,000 h-1. At 250 °C, CO may act as a reductant for NO reduction over Co/CNT in the presence of oxygen, whereas CO/NO = 2.5 showed that maximum NO reduction was 30%. Under H2 rich conditions, the optimum reaction temperature for CO conversion was under 300 °C, and performance of CO2 selectivity was better at 200 °C than 250 °C as the oxygen concentration increased.9enjournal article