CHIEN-HONG CHEN2026-10-162026-10-162023-01-16Pure ID: 15190896Pure UUID: 72b9ec13-7719-49b0-9643-0e275664526c10.1021/acs.inorgchem.2c03278https://www.scopus.com/pages/publications/85145454427https://scholars.csmu.edu.tw/handle/123456789/23205Continued efforts are made on the development of earth-abundant metal catalysts for dehydrogenation/hydrolysis of amine boranes. In this study, complex [K-18-crown-6-ether][(NO)2Fe(μ-MePyr)(μ-CO)Fe(NO)2] (3-K-crown, MePyr = 3-methylpyrazolate) was explored as a pre-catalyst for the dehydrogenation of dimethylamine borane (DMAB). Upon evolution of H2(g) from DMAB triggered by 3-K-crown, parallel conversion of 3-K-crown into [(NO)2Fe(N,N′-MePyrBH2NMe2)]− (5) and an iron-hydride intermediate [(NO)2(CO)Fe(μ-H)Fe(CO)(NO)2]− (A) was evidenced by X-ray diffraction/nuclear magnetic resonance/infrared/nuclear resonance vibrational spectroscopy experiments and supported by density functional theory calculations. Subsequent transformation of A into complex [(NO)2Fe(μ-CO)2Fe(NO)2]− (6) is synchronized with the deactivated generation of H2(g).13enjournal article