CHIEN-HONG CHEN2026-10-162026-10-162019-01-01Pure ID: 15096603Pure UUID: fb449280-4709-4b63-9905-46f7e1aa06aa10.1039/c8dt04714fhttps://www.scopus.com/pages/publications/85065516403https://scholars.csmu.edu.tw/handle/123456789/28921Reaction of compounds [(NO)2Fe(TMEDA)] and [BH4]- affords the first hydride-containing dinitrosyl iron complex (DNIC) [(NO)2Fe(η2-BH4)]- (2). Hydride-insertion reactivity of DNIC 2 promotes the reductive transformation of CS2 into DNIC [(NO)2Fe(η3-HCS2)]-, the first DNIC featuring both linear/bent NO ligands and Fe 3d z2-to-HCS2 π∗ backbonding interaction.6enjournal article