CHI-JUNG SU2026-10-162026-10-161997-01-01Pure ID: 15285878Pure UUID: 249d1f90-9bd6-41d8-892a-f4f0a168e4d410.1023/A:1022653029796https://www.scopus.com/pages/publications/0042732892https://scholars.csmu.edu.tw/handle/123456789/26789The hexaruthenium cluster compound Ru6(μ3-H)(CO)15[C5H 4(SiMe3)] (2), possessing two μ4-η2-CO ligands and with the Ru[C5H4(SiMe3)] fragment located at the apex of the central tetrahedral framework, was prepared in low yield by refluxing a toluene solution of C5H5(SiMe3) with excess Ru3(CO)12. This unique complex was characterized by spectroscopic methods and by X-ray structural analysis. The possible mechanism leading to its formation is discussed.13enjournal article